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Do-It-Yourself Transfer of Large-Area Graphene Using an Office Laminator and Water
Shivayogimath, Abhay1,2,9; Whelan, Patrick Rebsdorf1,2,3,9; Mackenzie, David M. A.1,2,10; Luo, Birong1,11; Huang, Deping4; Luo, Da5; Wang, Meihui6; Gammelgaard, Lene1,2,9; Shi, Haofei4; Ruoff, Rodney S.5,6,7,8
2019-04-09
摘要We demonstrate a simple method for transferring large areas (up to A4-size sheets) of CVD graphene from copper foils onto a target substrate using a commercially available polyvinyl alcohol polymer foil as a carrier substrate and commercial hot-roll office laminator. Through the use of terahertz time-domain spectroscopy and Raman spectroscopy, large-area quantitative optical contrast mapping, and the fabrication and electrical characterization of similar to 50 individual centimeter-scale van der Pauw field effect devices, we show a nondestructive technique to transfer large-area graphene with low residual doping that is scalable, economical, reproducible, and easy to use and that results in less doping and transfer-induced damage than etching or electrochemical delamination transfers. We show that the copper substrate can be used multiple loss of material and no observable reduction in graphene quality. We have additionally demonstrated the transfer of multilayer hexagonal boron nitride from copper and iron foils. Finally, we note that this approach allows graphene to be supplied on stand-alone polymer supports by CVD graphene manufacturers to end users, with the only equipment and consumables required to transfer graphene onto target substrates being a commercial office laminator and water.
DOI10.1021/acs.chemmater.8b04196
发表期刊CHEMISTRY OF MATERIALS
ISSN0897-4756
卷号31期号:7页码:2328-2336
通讯作者Booth, Timothy J.(tibo@dtu.dk)
收录类别SCI
WOS记录号WOS:000464477100015
语种英语