KMS Chongqing Institute of Green and Intelligent Technology, CAS
Complex alloying effect on thermoelectric transport properties of Cu2Ge(Se1-xTex)(3) | |
Wang, Ruifeng1,3; Dai, Lu1,3; Yan, Yanci1,2; Peng, Kunling1,2; Lu, Xu2; Zhou, Xiaoyuan2; Wang, Guoyu1,3 | |
2018-06-01 | |
摘要 | To enhance the thermoelectric performance of Cu2GeSe3, a series of Te-alloyed samples Cu2Ge(Se1-xTex)(3) are synthesized and investigated in this work. It is found that the lattice thermal conductivity is reduced drastically for x = 0.1 sample, which may be attributed to the point defects introduced by alloying. However, for samples with x >= 0.2, the lattice thermal conductivity increases with increasing x, which is related to a less distorted structure. The structure evolution, together with the change in carrier concentration, also leads to a systemically change in electrical properties. Finally, a zT of 0.55@750 K is obtained for the sample with x = 0.3, about 62% higher than that for the pristine sample. |
关键词 | thermoelectric Cu2GeSe3 alloying distorted structure |
DOI | 10.1088/1674-1056/27/6/067201 |
发表期刊 | CHINESE PHYSICS B |
ISSN | 1674-1056 |
卷号 | 27期号:6页码:6 |
收录类别 | CSCD |
WOS记录号 | WOS:000435924000001 |
语种 | 英语 |