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Heavy metals in soils of Hechuan County in the upper Yangtze (SW China): Comparative pollution assessment using multiple indices with high-spatial-resolution sampling
Ni, Maofei1,2; Mao, Rong1; Jia, Zhongmin3,4; Dong, Ruozhu1; Li, Siyue1
2018-02-01
摘要In order to assess heavy metals (HMs) in soils of the upper Yangtze Basin, a very high-spatial-resolution sampling (582 soil samples) was conducted from Hechuan County, an important agricultural practice area in the Southwest China. Multiple indices including geoaccumulation index (I-geo), enrichment factor (EF), sediment pollution index (SPI) and risk index (RI), as well as multivariate statistics were employed for pollution assessment and source identification of HMs in soils. Our results demonstrated that the averages of eight HMs decreased in the following order: Zn (82.8 +/- 15.9) > Cr (71.6 +/- 12.2) > Ni (32.1 9.89) > Pb (27.6 +/- 13.8) > Cu (25.9 +/- 11.8) > As (5.48 +/- 3.42) > Cd (0.30 +/- 0.077) > Hg (0.082 +/- 0.092). Averages of HMs except Cd were lower than threshold value of Environmental Quality Standard for Soils, while 43% of total samples had Cd concentration exceeding the national standard, 1% of samples for Hg and 5% samples for Ni, moreover, Cd and Hg averages were much higher than their background levels. I-geo and EF indicated that their levels decreased as follows: Cd > Hg > Zn > Pb > Ni > Cu > Cr > As, with moderate enrichments of Cd and Hg. RI indicated that 61.7% of all samples showed moderate risk, while 6.5% of samples with greater than considerable risk due to human activities should be paid more attention. Multivariate analysis showed lithogenic source of Cu, Cr, Ni and Zn, while Cd and Hg were largely contributed by anthropogenic activities such as agricultural practices. Our study would be helpful for improving soil environmental quality in SW, China, as well as supplying modern approaches for other areas with soil HM pollution.
关键词Heavy metals Risk assessment Source identification Soil pollution Yangtze Basin
DOI10.1016/j.ecoenv.2017.11.009
发表期刊ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
ISSN0147-6513
卷号148页码:644-651
收录类别SCI
WOS记录号WOS:000429892700075
语种英语