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Indirect detection of alcoholic strength in spirits by fluorescence method using the polyethyleneimine capped ZnO QDs
Geng, Shou1; Lin, Shu Min1; Liu, Shi Gang1; Zhang, Wei2; Li, Nian Bing1; Luo, Hong Qun1
2016-11-29
摘要We synthesized polyethyleneimine capped ZnO quantum dots (PEI-ZnO QDs) which dispersed well in ethanol by using a two-step method. UV-visible absorption spectroscopy, photoluminescence, Fourier transform infrared spectroscopy, high resolution transmission electron microscope, and field emission scanning electron microscope were used to characterize the as-prepared PEI-ZnO QDs. It emitted green-yellow fluorescence (527 nm) for excitation at 355 nm. We used the PEI-ZnO QDs to determine the alcoholic strength because of its different property in water and ethanol which caused decrease in the PEI-ZnO QDs fluorescence intensity with increasing water content. With this method, we determined the alcoholic strength of different artificial samples with a linear range from 20% to 60% vol and detected commercial spirits with satisfactory results. (C) 2016 Elsevier B.V. All rights reserved.
关键词PEI capped ZnO QDs Alcoholic strength Fluorescence
DOI10.1016/j.snb.2016.06.043
发表期刊SENSORS AND ACTUATORS B-CHEMICAL
ISSN0925-4005
卷号236页码:591-596
通讯作者Luo, HQ (reprint author), Southwest Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Gorges Reservoir Reg 3, Chongqing 400715, Peoples R China. ; Zhang, W (reprint author), Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China.
收录类别SCI
WOS记录号WOS:000382229700071
语种英语