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Synthesis of sub-millimeter Bi-/multi-layer graphene by designing a sandwiched structure using copper foils
Zhao, Zhijuan1,2; Jia, Kunpeng3; Shaw, Jonathan C.2; Zhu, Zhenwei1; Wan, Wen1; Zhan, Linjie1; Li, Mengping2; Wang, Haosen2; Chen, Xiangping1; Li, Zhancheng4
2016-09-19
摘要Bernal-stacked (AB-stacked) bilayer graphene has been receiving significant attention because it has a tunable band-gap under an applied vertical electric field. Herein, we designed a sandwiched structure simply by embedding one piece of Cu sheet into a Cu pocket to establish an environment that suppresses Cu evaporation and ensures that both surfaces of Cu sheet are smooth to grow large-size bilayer graphene (BLG) and multilayer graphene (MLG). Single-diffusion and double-diffusion mechanisms help explain graphene growth on both the Cu pocket and the Cu sheet, respectively. On the basis of the double-diffusion mechanism, we prepared AB-stacked sub-millimeter BLG and MLG with diameters up to 603 mu m and 793 mu m, respectively. Our work regarding the improvement of the quality and single-crystal size of graphene domains helps broaden the potential applications in materials chemistry and microelectronic devices. Published by AIP Publishing.
DOI10.1063/1.4963351
发表期刊APPLIED PHYSICS LETTERS
ISSN0003-6951
卷号109期号:12页码:5
通讯作者Zhao, ZJ ; Cai, WW (reprint author), Xiamen Univ, Dept Phys, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China. ; Zhao, ZJ ; Kaner, RB (reprint author), Univ Calif Los Angeles, Calif NanoSyst Inst, Dept Chem & Biochem, Los Angeles, CA 90095 USA.
收录类别SCI
WOS记录号WOS:000384558700057
语种英语