KMS Chongqing Institute of Green and Intelligent Technology, CAS
Melt spinning synthesis of p-type skutterudites: Drastically speed up the process of high performance thermoelectrics | |
Guo, Lijie1; Wang, Guiwen1; Peng, Kunling1,2; Yan, Yanci1; Tang, Xiaodan1; Zeng, Min3,4,5; Dai, Jiyan3; Wang, Guoyu2; Zhou, Xiaoyuan1 | |
2016-04-15 | |
摘要 | In this study, via a home-made induction melting process combined with spark plasma sintering technique, we successfully synthesize the nanostructured skutterudites NdxYbyFe3CoSb12 (x + y = 1.0, x = 03, 0.4, 0.5, 0.6, 0.7) in less than 3 h, which is significantly faster than that of the solid state reaction (168 h) and the traditional melt spinning method (40 h). Systematical microstructures analysis of the sintered bulk materials reveals the largely refined matrix grains (100-300 nm) and ubiquitous YbSb precipitates (similar to 30 nm), resulting in a very low lattice thermal conductivity. A peak ZT up to 1.02 at 760 K is obtained for Nd0.6Yb0.4Fe3CoSb12 compound. (C) 2016 Elsevier Ltd. All rights reserved. |
关键词 | P-type Filled Skutterudites Melt-spinning Phonon Scattering Thermoelectric Properties |
DOI | 10.1016/j.scriptamat.2016.01.035 |
发表期刊 | SCRIPTA MATERIALIA |
ISSN | 1359-6462 |
卷号 | 116页码:26-30 |
收录类别 | SCI |
WOS记录号 | WOS:000372560300006 |
语种 | 英语 |