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Super-rapid Preparation of Nanostructured NdxFe3CoSb12 Compounds and Their Improved Thermoelectric Performance
Guo, Lijie1; Zhang, Yumeng1; Zheng, Yong1; Yao, Wei1; Wang, Guiwen1,2; Wang, Guoyu2; Zhou, Xiaoyuan1
2016-03-01
摘要We report super-rapid preparation of p-type NdxFe3CoSb12 (x = 0.8, 0.85, 0.9, 0.95, 1.0) skutterudite compounds via a homemade induction melting assembly inside a glovebox followed by spark plasma sintering. Compared with samples prepared by solid-state reaction, the processing time is dramatically reduced from 9 days to less than 3 h, which is also significantly faster than the traditional melt-spinning method (40 h). Furthermore, the thermal conductivity of the bulk samples was remarkably reduced due to the Nd filler and the increased grain-boundary density. The enhanced thermoelectric performance coupled with the drastically reduced processing time is of considerable significance for commercial-scale production of skutterudite-based thermoelectric materials.
关键词p-Type skutterudites single filler rapid preparation nanostructuring phonon scattering thermoelectric properties
DOI10.1007/s11664-015-3997-9
发表期刊JOURNAL OF ELECTRONIC MATERIALS
ISSN0361-5235
卷号45期号:3页码:1271-1277
通讯作者Zhou, XY (reprint author), Chongqing Univ, Coll Phys, Chongqing 401331, Peoples R China. ; Wang, GY (reprint author), Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China.
收录类别SCI
WOS记录号WOS:000371163400010
语种英语