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Largely improved thermal conductivity and flame resistance of phase change materials based on three-dimensional melamine foam/phosphorous cellulose/graphite nanoplatelets network with multiple energy transition abilities
Xue, Fei1,2; Huang, Chen-hui1; Qi, Xiao-dong1; Yang, Jing-hui1; Zhao, Cheng-shou3; Lei, Yan-zhou4; Wang, Yong1
2022-05-01
摘要Solid-liquid organic phase change materials (OPCMs) appeal tremendous attention in thermal energy storage and management for their various merits. However, low thermal conductivity (TC), inferior encapsulation ability and fatal fire hazard significantly impair the application accessibility of the OPCMs. This work designed and fabricated a new three-dimensional (3D) melamine foam (MF)/phosphorous cellulose (PC)/graphite nanoplatelets (GNPs) (MF/PC/GNP) network to compound with the OPCMs with all these problems simultaneously sovled. With the assistance of MF-modified ice-templated method and PC, the GNPs form a dense network to efficiently enhance the TC of the composite PCMs to 1.08 W/(m.K) at a relatively low content of 2.39 wt%, while the electric conductivity (EC) reaches 0.690 S/cm. In addition, the peak of heat release rate (PHRR) of the composite PCMs decreases from 725.62 kW/m(2) of pure PEG to 624.04 kW/m(2). Besides, the MF/PC/GNP network also endows the composite PCMs with multiple energy-transition aiblities.
关键词Energy materials 3-Dimensional reinforcement Thermal properties Flame retardancy
DOI10.1016/j.compositesa.2022.106898
发表期刊COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
ISSN1359-835X
卷号156页码:11
通讯作者Wang, Yong(yongwang1976@swjtu.edu.cn)
收录类别SCI
WOS记录号WOS:000793521100002
语种英语