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Effect of Ce addition on the high-temperature oxidation resistance of Mg-Gd alloys
Yu, Xiaowen1,2; Li, Jing2; Jiang, Bin3; Yang, Chuan1,4; Yang, Jiping1; Chen, Sanxing1
2022-05-09
摘要In the present study, the oxidation resistance of magnesium alloyed with Gd and Ce was investigated. The high-temperature oxidation resistance of Mg-3.5Gd-xCe (x = 0, 0.2, 0.4, 0.7 and 1.0 wt%) alloys was evaluated at temperatures between 550 degrees C and 650 degrees C. Results indicate that adding less than 0.7 wt% Ce resulted in high oxidation resistance, whereas the Ce addition exceeding 0.7 wt% deteriorated the oxidation resistance. The high oxidation resistance phenomenon is attributed to the formation of compact oxide films primarily composed of MgO, Gd2O3, and a small amount of CeO2 on the surface of Mg-3.5Gd-0.2Ce and Mg-3.5Gd-0.4Ce alloys. These compact oxide films can prevent the matrix from experiencing further oxidation. The deteriorated oxidation resistances of Mg-3.5Gd-0.7Ce and Mg-3.5Gd-1Ce alloys were found to be due to the severe internal oxidation caused by the distributed Mg12Ce phases along the grain boundaries.
关键词Ce Gd Mg oxidation oxide film
DOI10.1002/maco.202113005
发表期刊MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
ISSN0947-5117
页码10
通讯作者Yang, Chuan(yang5103@tom.com)
收录类别SCI
WOS记录号WOS:000792451200001
语种英语