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Influence of Different Electrolyte Additives and Structural Characteristics of Plasma Electrolytic Oxidation Coatings on AZ31 Magnesium Alloy
Huang, Zhiquan1; Wang, Ruiqiang2,3; Liu, Xintong1,4; Wang, Dongdong1; Zhang, Heng5; Shen, Xiaojie6; Shen, Dejiu1; Li, Dalong7
2020-09-01
摘要Coatings prepared by different electrolyte additives were investigated on AZ31 magnesium alloy by plasma electrolytic oxidation. In this study, scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction analysis were employed to assess the morphologies, chemical and phase compositions of the plasma electrolytic oxidation (PEO) coatings, respectively. Furthermore, electrochemical impedance spectroscopy was used to evaluate the corrosion behavior of the composite coating. The investigation of the effect of electrolyte additives in the base electrolyte showed that the PEO specimens exhibit different surface and cross-sectional morphologies, and phase compositions. The results showed that SiO32- was conducive to the growth of the ceramic layer, and the ceramic layer developing in the electrolyte which contained AlO2- showed a typical double-layer structure. The corrosion resistance of coating formed in a phosphate bath was higher than that of the coating formed in silicate bath and coating formed in an aluminate bath. Moreover, the corrosion resistance of the coating formed in the fluoride bath was the highest.
关键词magnesium alloy plasma electrolytic oxidation electrolyte additive corrosion behavior
DOI10.3390/coatings10090817
发表期刊COATINGS
卷号10期号:9页码:11
通讯作者Li, Dalong(gmzhang@ysu.edu.cn)
收录类别SCI
WOS记录号WOS:000581375800001
语种英语