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A 9,9 '-bifluorenylidene derivative containing four 1,1-dicyanomethylene-3-indanone end-capped groups as an electron acceptor for organic photovoltaic cells
Yu, Tianzhi1; Yang, Qianguang1; Zhang, Tong1; Zhao, Yuling2; Wei, Chengjin1; Li, Yanmei1; Zhang, Hui1; Hu, Dingqin3
2019-12-14
摘要A 9,9 '-bifluorenylidene derivative, 2,2 ',2 '',2 '''-([9,9 '-bifluorenylidene]-2,2 ',7,7 '-tetrayltetrakis(4-octylthiophene-5,2-diyl))tetrakis(methanylylidene)tetrakis(3-oxo-2,3-dihydro-1H-indene-2,1-diylidene)tetramalononitrile (BF-TDCI4), was synthesized as an electron acceptor for organic photovoltaic cells. Its photophysical and electrochemical properties and thermal stability were investigated systematically. The photovoltaic devices were fabricated using PTB7-Th as the electron donor and BF-TDCI4 as the electron acceptor at various composition ratios. The optimized device exhibited a maximum power conversion efficiency of 4.35% with an open-circuit voltage of 0.87 V.
DOI10.1039/c9nj02604e
发表期刊NEW JOURNAL OF CHEMISTRY
ISSN1144-0546
卷号43期号:46页码:18110-18119
通讯作者Yu, Tianzhi(yutzh@mail.lzjtu.cn) ; Hu, Dingqin(hudingqin@cigit.ac.cn)
收录类别SCI
WOS记录号WOS:000499476200023
语种英语